Measuring Keq Lab

Measuring Keq-1ko7bqc

Measuring Keq

Part I:  Preparation of a standard absorption curve for FeSCN+2

Standard 0.20M Fe(NO3)3 0.0020 M KSCN 0.100M HNO3 [FeSCN+2] Absorbance
A 10.0 mL 0.0 mL 15.0 mL 0M 0.000
B 10.0 mL 1.0 mL 14.0 mL 8.00×10^-5M 0.307
C 10.0 mL 1.5 mL 13.5 mL 1.20×10^-4M 0.446
D 10.0 mL 2.0 mL 13.0 mL 1.60×10^-4M 0.616
E 10.0 mL 2.5 mL 12.5 mL 2.00×10^-4M 0.815
F 10.0 mL 3.0 mL 12.0 mL 2.40×10^-4M 0.965

EQUATION:     y=3966.9x                                                                            R2 0.9968

Part 2: Measuring Equilibrium

Test Solution 0.0020 M Fe(NO3)3 0.0020 M

KSCN

0.10 M

HNO3

Initial [Fe+3] Initial [SCN] Absorbance Equilibrium

[FeSCN+2]*

I 5.0 mL 0 5.0 mL 0.0010M 0M 0 0M
II 5.0 mL 1.0 mL 4.0 mL 0.0010M 2.0×10^-4M 0.172 4.33×10^-5M
III 5.0 mL 2.0 mL 3.0 mL 0.0010M 4.0×10^-4M 0.404 1.02×10^-4M
IV 5.0 mL 3.0 mL 2.0 mL 0.0010M 6.0×10^-4M 0.642 1.62×10^-4M
V 5.0 mL 4.0 mL 1.0 mL 0.0010M 8.0×10^-4M 0.845 2.13×10^-4M
VI 5.0 mL 5.0 mL 0.0 mL 0.0010M 1.0×10^-3M 0.904 2.28×10^-4M

 

* To be determined from the standard graph equation.

ANALYSIS:

  1. Use your graph equation to calculate the equilibrium concentrations of FeSCN+2.
  2.  Prepare and ICE chart for each test solution (II – VI) and calculate the value of Keq for each of your 5 tests solutions.

ICE CHART 1

Test Solution

Keq =282

Fe3+               +                SCN–                    ⇄            FeSCN2+
I 0.0010 0.00020 0
C -0.0000433 -0.0000433 +0.0000433
E 0.00096 0.00016 0.0000433

 

ICE CHART 2

Test Solution

Keq =378

Fe3+               +                SCN–                    ⇄            FeSCN2+
I 0.0010 0.00040 0
C -0.000102 -0.000102 +0.000102
E 0.00090 0.00030 0.000102

 

ICE CHART 3

Test Solution

Keq =444

Fe3+               +                SCN–                    ⇄            FeSCN2+
I 0.0010 0.00060 0
C -0.000162 -0.000162 +0.000162
E 0.00083 0.00044 0.000162

 

ICE CHART 4

Test Solution

Keq =444

Fe3+               +                SCN–                    ⇄            FeSCN2+
I 0.0010 0.00080 0
C -0.000213 -0.000213 +0.000213
E 0.00080 0.00060 0.000213

 

ICE CHART 5

Test Solution

Keq =384

Fe3+               +                SCN–                    ⇄            FeSCN2+
I 0.0010 0.0010 0
C -0.000228 -0.000228 +0.000228
E 0.00077 0.00077 0.000228

 

CONCLUSION AND EVALUATION:

  1. Comment on your Keq values.   Do your results convince you that Keq is a constant value regardless of the initial concentrations of the reactants?  Why or why not?

Yes, because most of the values we got for Keq are fairly close to each other.

  1. Calculate the average value of Keq from your five trials.  The actual value of Keq for this reaction at 25oC is reported as 280.   Calculate (should you use all of your values?) the percent difference of your average value from the reported value:

% difference = (experimental value – reported value)  x 100%

Reported value

Average = Keq1 + Keq2 + Keq3 + Keq4 + Keq5

5

Average = 282 +378 + 444 + 444 + 384  = 386

5

% difference = (386-280) x 100% = 37.9%

280

Physics 11 – Newton’s Laws

This first video represents Newton’s first law: Inertia. An object will stay in motion, and an object at rest will stay at rest. I used the cart to show an object in motion. According to Newton’s law, in perfect conditions, the cart will never stop rolling after I push it, but it will stop due to friction slowing it down (in the video it hit something). I used a weight to show that it will take more force to get the object to start moving, if I used more force it would have moved.

The second video represents Newton’s second law: F=ma. This law shows the relationship between Net Force, Mass, and Acceleration. You can use this equation to calculate how much force it would take to accelerate an object with a certain mass at that speed. I used two pineapples with different masses. To get both of the pineapples to accelerate at the same speed I would need to apply more force to the heavier pineapple. If I were to use the same force on each of the pineapples, the smaller one would accelerate faster than the larger one. Another example, is if you had two cars, one heavier than the other, it would take more force to move the larger car at the same speed of the smaller one.

This last video shows a example of Newton’s third law: F1=-F2. Every action will have an equal and opposite reaction. With an object resting on the ground, you would have the force of gravity pushing downwards, and also the normal force, equal to the gravitational force, holding the object up. In my example, I used a ball of silly putty to show the opposite force, when the ball hits the desk, it bounces back upwards. But then why, for example, does my textbook not bounce when I drop it? The bouncing happens die to the elasticity of the object, it depends on the objects ability to deform and reform upon impact, even if the object does not bounce, the upward force is still there.

Measurement

Today in math class we learned about measurement. We talked about what systems we use today, mostly the metric system and the imperial system, but we also talked about referents that are used too, and that where also used a long time ago, for example we talked about paces, and hands. We also learned that the first unit of measurement known to be used was the cubit, and it was used back in Ancient Egypt.

Graphs of Exponential Functions

Explanation

I was in group 4 so we needed to solve and graph the equation “y = 3^-x”, where x was equal to -10-10. The distances between the points represent the differences of what “y” is equal to when using the different powers. We also needed to compare our graph to the graph of group 3 who had the equation “y = 3^x”. Both the graphs where opposites of each other, so they where both flipped on the y-axis.                                                                                     win_20160927_14_28_45_pro

What did I learn?

I learned about the similarities with equations that use the same base, but different exponents. I also learned how inverting the exponent will affect how the graph will look, and how to identify the similarities between two graphs.

Pas de Sens- Les Films

ChickenPas de Sens

Ici je parle des chose qui ne fait aucun de sens et je parle de pourquoi c’est stupide.

Les Filmes

Ici je parle des scenes des filmes qui ne fait pas de sens et qui sont completement stupides.

https://sd43-my.sharepoint.com/personal/132-tjang_office43_ca/_layouts/15/guestaccess.aspx?guestaccesstoken=PHcf2k48F3abECIs38LWIpjmgkog22kSpUuAr

j8eeEk%3d&docid=0864d81a41a54477fb05a3f222faaec2a

 

Batailles Des Restaurants Rapides Ep.4 -Les Sandwichs

 

AMAZING LOGO

Les Batailles Des Restaurants Rapides

Ici ont compare les nourritures different et on vas decider quelle est le mieux de tous!

Ep.4- Les Sandwichs

Ici on vas comparer deux restaurants de sandwichs, le Quiznos et le Subway, ca vas etre tres excitant tu devrais le regarder maintenant!

https://sd43-my.sharepoint.com/personal/132-tjang_office43_ca/_layouts/15/guestaccess.aspx?guestaccesstoken=IhKi5z5zV2OlW9%2fdMw0UKro8wWYe8hzIwTZg%2bMJb9tI%3d&docid=070be22259dae4827a6c1edeb499418cd

Batailles Des Restaurants Rapides -ep.2 A&W

 

 

Logo

 

Batailles des Restaurants Rapides

Ici on va discuter les options sur les menue des restaurants rapides et on vas decider quelle est la meilleur de tous.

Ep.2 -A&W

Aujourd’hui on va decider quesce que c’est la meilleur le petit dejeuner ou le diner au A&W ca vas etre un bataille tres extrodinaire et excitant vous ne pouvez pas sauter cette bataille.

https://sd43-my.sharepoint.com/personal/132-tjang_office43_ca/_layouts/15/guestaccess.aspx?guestaccesstoken=hnqDex5xK9kjOVM%2bnHleqwoVT5SLj3wqhNcvMUPFJao%3d&docid=09dbbbdece85a4d1799f615aaab494727