Part I: Preparation of a standard absorption curve for FeSCN+2
Standard | 0.20M Fe(NO3)3 | 0.0020 M KSCN | 0.100M HNO3 | [FeSCN+2] | Absorbance |
A
|
10.0 mL | 0.0 mL | 15.0 mL | 0 M | 0 |
B
|
10.0 mL | 1.0 mL | 14.0 mL | 0.00008 M | 0.293 |
C
|
10.0 mL | 1.5 mL | 13.5 mL | 0.00012 M | 0.482 |
D
|
10.0 mL | 2.0 mL | 13.0 mL | 0.00016 M | 0.650 |
E
|
10.0 mL | 2.5 mL | 12.5 mL | 0.0002 M | 0.845 |
F
|
10.0 mL | 3.0 mL | 12.0 mL | 0.00024 M | 1.040 |
EQUATION: y = 4353.9x – 0.0289 R2: 0.9964
Part 2: Measuring Equilibrium
Test Solution | 0.0020 M Fe(NO3)3 | 0.0020 M
KSCN |
0.10 M
HNO3 |
Initial [Fe+3] | Initial [SCN–] | Absorbance | Equilibrium
[FeSCN+2]* |
I
|
5.0 mL | 0 | 5.0 mL | 0.001 M | 0 | 0 | 0 |
II
|
5.0 mL | 1.0 mL | 4.0 mL | 0.001 M | 0.0002 | 0.204 | 0.0000535 |
III
|
5.0 mL | 2.0 mL | 3.0 mL | 0.001 M | 0.0004 | 0.342 | 0.0000852 |
IV
|
5.0 mL | 3.0 mL | 2.0 mL | 0.001 M | 0.0006 | 0.518 | 0.000126 |
V
|
5.0 mL | 4.0 mL | 1.0 mL | 0.001 M | 0.0008 | 0.802 | 0.000191 |
VI
|
5.0 mL | 5.0 mL | 0.0 mL | 0.001 M | 0.001 | 1.025 | 0.000242 |
* To be determined from the standard graph equation.
ANALYSIS:
- Use your graph equation to calculate the equilibrium concentrations of FeSCN+2
ii) 0.0000535
iii) 0.0000852
iv) 0.000126
v) 0.000191
vi) 0.000242
- Prepare and ICE chart for each test solution (II – VI) and calculate the value of Keq for each of your 5 tests solutions.
ii)
Keq = 384 |
Fe3+ + SCN– ⇄ FeSCN2+ | ||
I
|
0.001 | 0.0002 | 0 |
C
|
– 0.0000535 | – 0.0000535 | 0.0000535 |
E
|
0.000947 | 0.000147 | 0.0000535 |
iii)
Keq = 296 |
Fe3+ + SCN– ⇄ FeSCN2+ | ||
I
|
0.001 | 0.0004 | 0 |
C
|
– 0.0000852 | – 0.0000852 | 0.0000852 |
E
|
0.000915 | 0.000315 | 0.0000852 |
iv)
Keq = 304 |
Fe3+ + SCN– ⇄ FeSCN2+ | ||
I
|
0.001 | 0.0006 | 0 |
C
|
– 0.000126 | – 0.000126 | 0.000126 |
E
|
0.000874 | 0.000474 | 0.000126 |
v)
Keq = 387 |
Fe3+ + SCN– ⇄ FeSCN2+ | ||
I
|
0.001 | 0.0008 | 0 |
C
|
– 0.000191 | – 0.000191 | 0.000191 |
E
|
0.000810 | 0.000610 | 0.000191 |
vi)
Keq = 421 |
Fe3+ + SCN– ⇄ FeSCN2+ | ||
I
|
0.001 | 0.001 | 0 |
C
|
– 0.000242 | – 0.000242 | 0.000242 |
E
|
0.000758 | 0.000758 | 0.000242 |
CONCLUSION AND EVALUATION:
- Comment on your Keq values. Do your results convince you that Keqis a constant value regardless of the initial concentrations of the reactants? Why or why not?
Even though all the Keqvalues of the five solutions weren’t exactly the same they were close enough to assume that Keq is a constant value.
- Calculate the average value of Keqfrom your five trials. The actual value of Keq for this reaction at 25oC is reported as 280. Calculate (should you use all of your values?) the percent difference of your average value from the reported value:
% Difference = (experimental value – reported value) x 100%
Reported value
Average Keq: 358.4
% Difference = (358.4 – 280)x 100% = 28%
280